Molecular Spectroscopy of Oxide Catalyst Surfaces Tapa dura - 2003
de Anatoli Davydov
Primera línea
Numerous technological processes are dependent on the nature of the molecular and chemical interactions which occur on contact of various media with solid surfaces.
Descripción de contraportada
As in the study of transition metal complexes in solution, molecular spectroscopic methods - principally the infrared, ultraviolet/visible and electron spin resonance spectroscopies - have played key roles in establishing the concepts of coordination chemistry occurring at the surfaces of solids. This book describes the development of the principals of coordination chemistry of oxide surfaces using analyses of data obtained by these methods. The nature, properties, concentration of the surface adsorption centers and their influence on the character of interaction with different molecules are investigated. The book commences with an account of the basic theoretical principles and experimental techniques of the various spectroscopy methods, with special attention devoted to in situ measurements where the oxide or catalyst sample is in contact with the adsorbate or the reactant. A detailed account is presented of the methods for characterizing the oxidation state and degree of coordination of surface cations and oxygen anions by the adsorption of probe molecules. The complexation of many inorganic, organometallic and organic molecules with different oxide systems is critically examined, and a classification of formed surface compounds, based on the interaction with definite type of adsorption centers, is given. Possible mechanisms of numerous catalytic reactions, including the transformation of organic molecules over acidic catalysts via the carboionic mechanism, are discussed using the spectroscopic identifications of reaction intermediates. A comprehensive analysis of the literature on the interpretation of the spectra of surface compounds on oxides is presented. This highly illustrated and extensively referenced volume is intended for specialists working in the fields of surface physical chemistry, surface and materials sciences, and adsorption phenomena and is essential reading for those involved in the heterogeneous catalysis by transition metal-oxides.
Detalles
- Título Molecular Spectroscopy of Oxide Catalyst Surfaces
- Autor Anatoli Davydov
- Encuadernación Tapa dura
- Páginas 690
- Volúmenes 1
- Idioma ENG
- Editorial Wiley
- Fecha de publicación 2003
- Ilustrado Sí
- Features Bibliography, Illustrated, Index
- ISBN 9780471987314 / 047198731X
- Peso 2.84 libras (1.29 kg)
- Dimensiones 9.84 x 6.9 x 1.64 pulgadas (24.99 x 17.53 x 4.17 cm)
- Library of Congress subjects Molecular spectroscopy, Metallic oxides - Surfaces - Analysis
- Número de catálogo de la Librería del Congreso de EEUU 2002191080
- Dewey Decimal Code 541.33
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Molecular Spectroscopy of Oxide Catalyst Surfaces
de A A Davydov Anatoli Davydov
- Nuevo
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- ISBN 10 / ISBN 13
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Mostrar detalles
Molecular Spectroscopy in Oxide Surface Chemistry
de Davydov, A. A./ Shepard, N. T./ Shepard, N. T. (Editor)
- Nuevo
- Tapa dura
- Estado
- New
- Encuadernación
- Hardcover
- ISBN 10 / ISBN 13
- 9780471987314 / 047198731X
- Cantidad disponible
- 1
- Librería
-
Exeter, Devon, United Kingdom
- Precio
-
EUR 577.24EUR 11.84 enviando a USA